Intercalation of 2,4-dihydroxybenzophenone-5-sulfonate anion into Zn/Al layered double hydroxides for UV absorption properties

Shifeng Li; Yanming Shen; Min Xiao; Dongbin Liu; Lihui Fa; Keke Wu

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 1280-1284, July, 2014

DOI10.1016/j.jiec.2013.07.006 Export Citation

Intercalation of 2,4-dihydroxybenzophenone-5-sulfonate anion into Zn/Al layered double hydroxides for UV absorption properties

Shifeng Li^†, Yanming Shen, Min Xiao¹, Dongbin Liu, Lihui Fa, and Keke Wu

Liaoning Provincial Key Laboratory of Chemical Separation Technology, College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
¹Department of Environmental Engineering, Shenyang University, Shenyang 110044, China

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Zn/Al-layered double hydroxides (LDHs) containing the organic anion of 2,4-dihydroxybenzophenone-5-sulfonate (DHBS) have been synthesized by co-precipitation method. Surface, structural, thermal and absorption properties of the ZnAl-DHBS-LDHs nanohybrids were characterized by BET analysis, scanning electron microscope, X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetry and differential thermal analysis and UV-visible spectroscopy. The results revealed that organic UV absorbent-DHBS has been intercalated into the interlayer spaces of ZnAl-LDHs and the intercalation of DHBS in LDHs interlayer galleries resulted to higher thermal stability and better UV absorption ability; these show that the hybrid ZnAl-DHBS-LDHs phase has potential applications as a UV absorber.

Keywords:Layered double hydroxide;Intercalation;UV absorbent;Photochemical properties;2,4-Dihydroxybenzophenone-5-sulfonate

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[Referenced By]

[1] Diffey BL, Phys. Med. Biol., 36, 299 (1991)

[2] Neades R, Cox L, Pelling JC, Mol. Carcinogenesis, 23, 159 (1998)

[3] El-Toni AM, Yin S, Sato T, Mater. Lett., 58, 3149 (2004)

[4] Duan X, Evans DG, Layered Double Hydroxides, Springer, Berlin, 2006.

[5] Kim MJ, Kim H, Jeong KE, Jeong SY, Park YK, Jeon JK, J. Ind. Eng. Chem., 16(4), 539 (2010)

[6] Dixit M, Mishra M, Joshi PA, Shah DO, J. Ind. Eng. Chem., 19(2), 458 (2013)

[7] Yu X, Luo T, Jia Y, Xu R, Gao C, Zhang Y, Liu J, Huang X, Nanoscale, 4, 3466 (2012)

[8] Jin L, Liu Q, Sun ZY, Ni XY, Wei M, Ind. Eng. Chem. Res., 49(22), 11176 (2010)

[9] Hussein MZ, Rahman NSSA, Sarijo SH, Zainal Z, Appl. Clay Sci., 58, 60 (2012)

[10] He Q, Yin S, Sato T, J. Phys. Chem. Solids, 65, 395 (2004)

[11] El-Toni AM, Yin S, Sato T, Mater. Chem. Phys., 89(1), 154 (2005)

[12] Li D, Tuo Z, Evans DG, Duan X, J. Solid State Chem., 179, 3114 (2006)

[13] Feng Y, Li D, Wang Y, Evans DG, Duan X, Polym. Degrad. Stabil., 91, 789 (2006)

[14] Sun W, He Q, Luo Y, Mater. Lett., 61, 1881 (2007)

[15] Zhang L, Lin Y, Tuo Z, Evans DG, Li D, J. Solid State Chem., 180, 1230 (2007)

[16] Perioli L, Nocchetti M, Ambrogi V, Latterini L, Rossi C, Costantino U, Microporous Mesoporous Mater., 107, 180 (2008)

[17] Sun W, He Q, Lu L, Liu H, Mater. Chem. Phys., 107(2-3), 261 (2008)

[18] Chai H, Lin YJ, Evans DG, Li DQ, Ind. Eng. Chem. Res., 47(9), 2855 (2008)

[19] Chai H, Xu X, Lin Y, Evans DG, Li D, Polym. Degrad. Stabil., 94, 744 (2009)

[20] Cursino ACT, Gardolinski JEFD, Wypych F, J. Colloid Interface Sci., 347(1), 49 (2010)

[21] Cui GJ, Xu XY, Lin YJ, Evans DG, Li DQ, Ind. Eng. Chem. Res., 49(2), 448 (2010)

[22] Cui G, Evans DG, Li D, Polym. Degrad. Stabil., 95, 2082 (2010)

[23] Sher BK, Liu C, Eui SJ, Akhtar K, Han H, Mater. Lett., 65, 2923 (2011)

[24] Zhu HF, Feng YJ, Tang PG, Cui GJ, Evans DG, Li DQ, Duan X, Ind. Eng. Chem. Res., 50(23), 13299 (2011)

[25] Coelho C, Hennous M, Verney V, Leroux F, RSC Adv., 2, 5430 (2012)

[26] Kaidbey K, Grange RW, J. Am. Academy Dermatol., 16, 346 (1987)

[27] Kunisue T, Wu Q, Tanabe S, Aldous KM, Kannan K, Anal. Methods, 2, 707 (2010)

[28] Allan JV, Tinker JF, J. Org. Chem., 19, 1243 (1954)

[29] Kloprogge JT, Frost RL, J. Solid State Chem., 146, 506 (1999)

[30] Li F, Zhang FH, Evans DG, Forano C, Duan X, Thermochim. Acta, 424(1-2), 15 (2004)

[31] Sun GB, Sun LN, Wen H, Jia ZQ, Huang KL, Hu CW, J. Phys. Chem. B, 110(27), 13375 (2006)

[32] Shao M, Ning F, Zhao Y, Zhao J, Wei M, Evans DG, Duan X, Chem. Mater., 24, 1192 (2012)

[33] Hu J, Ren L, Guo Y, Liang H, Cao A, Wan L, Bai C, Angew. Chem.-Int. Edit., 44, 1269 (2005)

[34] bin Hussein MZ, Long CW, Mater. Chem. Phys., 85(2-3), 427 (2004)

[35] Mark J, Boltom JR, J. Photochem. Photobiol. A-Chem., 128, 1 (1999)