Journal of Chemical Physics, Vol.100, No.9, 6934-6943, 1994
Micelle Formation, Relaxation-Time, and 3-Phase Coexistence in a Microemulsion Model
Our Larson-type microemulsion model for surfactant chains in oil-water solvents leads to long relaxation times as well as, for essential modifications, to a stable peak in the chain-cluster size distribution. Transfer energies for surfactant chains moving to the oil-water interface, and characteristic micelle concentrations (CMC) as a function of chain length are compared with experiment.