화학공학소재연구정보센터
Journal of Chemical Physics, Vol.101, No.2, 869-875, 1994
The Normal to Local Mode Transition in Ab(2) Triatomic-Molecules - The Susceptibility of Eigenstates to Symmetry-Breaking Perturbations
We argue that the physical significance of the normal to local mode transition in triatomic molecules AB(2) lies in an enhanced susceptibility of eigenstates to symmetry breaking perturbations. States of local character have higher susceptibilities than states of normal character. The quantum mechanical condition for the normal to local mode transition is formulated. The issue of stability is addressed from a classical, semiclassical, and quantum, mechanical point of view. The question of instability of the unperturbed quantum system is decided individually for each eigenstate. The relevance for experiments is outlined.