The objective of this study is to compare the performance of several activated carbon (AC) based catalysts for CH4 reforming with CO2, including raw AC and AC modified with HNO3 and NaNO3, designated as AC-HNO3 and AC-NaNO3, respectively. CH4-CO2 reforming experiments were conducted in a fixed-bed reactor at temperatures from 700 degrees C to 1000 degrees C. The catalysts were characterized by various techniques, including Fourier Transform Infrared Spectroscopy (FTIR), Brunauer-Emmett-Teller (BET) analysis, CO2 chemisorption, temperature programmed oxidation-CO2 (TPO-CO2), and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX). The catalytic activities of the three catalysts are considerably different at low temperature, although they are similar at high temperature. At 700 degrees C, the average conversions of CH4 and CO2 over AC-NaNO3 are 17.7% and 29.7%, respectively, which are 2.4 and 3.2 times higher than those over AC. At 1000 degrees C, the conversions of CH4 and CO2 exceed 90% over these three catalysts. In addition, the mole ratio of H-2/CO increases with temperature for all the catalysts. The mole ratio of H-2/CO over AC-HNO3, which is from 0.76 to 0.94 at different temperatures, is closer to I than that over the other two catalysts. Based on the characterization results, NaNO3 is more instrumental to the formation of mesopores, surface oxygenated groups, and the reduction of deposited carbon. Hydroxyl group plays an important role in CH4-CO2 reforming. According to TPO-CO2 observations, two types of deposited carbon are formed during reforming reaction. The apparent activation energies of the CH4-CO2 reforming reactions catalyzed by AC, AC-HNO3, and AC-NaNO3 are 202 kJ/mol, 227 KJ/mol, and 123 kJ/mol. (C) 2013 Elsevier B.V. All rights reserved.