A metal organic framework encapsulated gold nanoparticles noted as Au/UiO-66 were developed through double solvents method. Highly dispersed Au nanoparticles were presented within the pores of metalorganic framework (MOF) UiO-66 without deposition of the nanoparticles on the external surface or aggregation. With benzyl alcohol as substrate, Au/UiO-66 exhibited excellent catalytic performance to afford benzaldehyde as the only product. The reactions which could be carried out under solvent-free conditions offered a green process with 02 of atmospheric pressure as oxidant. Water was proved to be beneficial for the reaction and the hydrophilic character of the MOF inner face facilitated its promotion effect greatly. The catalyst showed great stability and could be reused for at least eight times without obvious aggregation or leaching. (C) 2014 Elsevier B.V. All rights reserved.