Concentration polarization, a retarding effect upon hydrogen permeation across a membrane, will affect the performance of hydrogen separation. To recognize the concentration polarization behavior of hydrogen-rich gas in high-permeance membrane tubes, three palladium-based membranes with two pure palladium (Pd) membranes and one Pd-Cu alloy membrane are tested. Three important parameters, consisting of the H-2 partial pressure difference, the flow rate at the exit of the retentate side and the H-2 concentration in the feed gas mixture (H-2+N-2), are taken into account. A comparison to pure H-2 permeation suggests that the concentration polarization is clearly exhibited when the gas mixture is fed. Decreasing the H-2 concentration in the feed gas tends to deteriorate the polarization phenomenon. The sensitivity of polarization to H-2 concentration is higher when its concentration in the feed gas is larger. For the gas mixtures with 50 and 75 vol% of H-2, the permeances of the membranes are reduced by 1-2 orders of magnitude. The permeances of the membranes are also affected a bit when the H-2 partial pressure difference or the flow rate is altered. (C) 2013 Elsevier Ltd. All rights reserved.