Journal of Chemical Physics, Vol.101, No.5, 4150-4155, 1994
Microscopic Theory of Ion Solvation Dynamics in Liquid Methanol
A microscopic study of the solvation dynamics of a rigid ion in liquid methanol is presented. The theory is in good agreement with the available computer simulation results. We further find that the collective and single particle dissipative kernels (that is, the memory functions) show rather similar dynamics at ultrashort times.
Keywords:MOLECULAR-DYNAMICS;DIELECTRIC-RELAXATION;COMPUTER-SIMULATION;DIPOLAR LIQUIDS;POLAR-SOLVENTS;ACETONITRILE;SPECTROSCOPY;ELECTRON;MODEL