In this study, we describe the enhancing ability of electrospun polyurethane (PU) nanofibers containing carbon nanotubes (CNTs) as nanofillers for silicone film in improving the physico-mechanical properties of the composite material. We prepared the samples combining two simple techniques: solution casting and electrospinning. Neat PU nanofibers alone are good reinforcing materials but the presence of CNTs inside the PU nanofibers has drastically improved the mechanical properties of the silicone composite film. The silicone film increased its tensile strength by 226% and its tensile modulus by more than 14-fold when CNT/PU nanofibers were incorporated. (C) 2012 Elsevier B. V. All rights reserved.