Layer stacks of FePt(15 nm)/Ag(x)/FePt(15 nm) with various Ag interlayer thicknesses (x = 0, 3, and 30 nm) were deposited at room temperature onto SiO2(100 nm)/Si(0 0 1) substrates. These films were post-annealed in a temperature range of 100 degrees C-900 degrees C for 30 s under high vacuum condition. The influence of the Ag interlayer on the L1(0)(FePt)(FCT) phase formation and its related structural and magnetic properties were investigated. The onset of chemical ordering of FePt single layers is observed at annealing temperatures between 600 degrees C and 700 degrees C. Increasing the Ag interlayer thickness to 30 nm reduces the ordering temperature of the L1(0)(FePt)(FCT) phase formation by about similar to 100 degrees C. Higher annealing temperatures lead to a further increase in volume fraction of the ordered L1(0)(FePt)(FCT) phase but also to the diffusion of Ag towards the free surface as probed by secondary neutral mass spectrometry. In addition, due to the limited solvability of Ag into the FePt phase, Ag is expected to be located at the grain boundaries. The increasing volume fraction of the L1(0)(FePt)(FCT) phase is also reflected in the increasing coercivity of the films which reaches values of up to similar to 19 kOe after annealing at 900 degrees C. Furthermore, in this case similar M-H hysteresis loop were recorded when the field is applied in the film plane and perpendicular to it. This isotropic behavior is in agreement with the coexistence of L1(0) ordered grains which are randomly oriented. (c) 2012 Elsevier B.V. All rights reserved.