Applied Surface Science, Vol.284, 588-594, 2013
The effect of original crystalline phase on solid phase crystallization of hydrogenated silicon thin films
Hydrogenated amorphous silicon (a-Si:H) and microcrystalline silicon (mu c-Si:H) films fabricated on glass substrate are crystallized through solid phase crystallization process. In this study, the crystalline phase in mu c-Si:H films could decrease process temperature, but prevent the film from crystallized completely. In counterpart, the a-Si: H films need higher annealing temperature to achieve crystallization, but could reach a better crystallinity. The fact that mu c-Si:H films do not crystallize completely is attributed to the initial microcrystals in the mu c-Si:H films, which avoid the relaxation of the film structure and inhibit the crystallization process. In addition, the effusion of hydrogen could promote the relaxation of a-Si but not induce direct crystallization. (C) 2013 Elsevier B. V. All rights reserved.
Keywords:Solid phase crystallization;Hydrogenated amorphous silicon;Hydrogenated microcrystalline silicon;Thin film