Porous g-C3N4 (pm-g-C3N4) samples were prepared by sintering protonated melamine. Photocatalytic activities for H-2 production over the g-C3N4 samples were evaluated under visible-light irradiation. Specific surface areas and condensation degree of the g-C3N4 samples prepared from protonated melamine turn larger as the calcination temperatures increase (400 degrees C, 450 degrees C, 500 degrees C, 550 degrees C, and 580 degrees C for 1 h). Also, their bandgaps are narrowed and PL peak red shifts, and thus their photocatalytic activities are enhanced. Compared with the reference g-C3N4 samples synthesized by sintering melamine without any protonation (m-g-C3N4), the pm-g-C3N4 samples exhibit better photocatalytic performances, owing to larger specific surface area, less recombination of photogenerated carriers and higher degree of condensation. By optimizing the preparation parameters and the amount of Pt cocatalyst, the highest hydrogen evolution rate of 417 mu mol h(-1) g(-1) was achieved over the pm-g-C3N4 samples synthesized at 550 degrees C for 2 h, when irradiated by 300-W Xe lamp with a cutoff filter (lambda > 420 nm). (C) 2014 Elsevier B. V. All rights reserved.