We studied the spatiotemporal profiles of NO reduction with NH3, C3H6, or NH3 + C3H6 over a commercial Cu-chabazite SCR catalyst (washcoated honeycomb monolith) to better understand the effects of C3H6 on NO reduction under fast lean/rich cycling conditions relevant to coupled LNT-SCR catalysts. NO reduction by NH3 was very effective with total NH3 consumption within the first quarter of the catalyst at all temperatures. By contrast, NO reduction by C3H6 was more gradual along the catalyst length and sensitive to temperature with maximum performance obtained at 300-400 C. Temperatureprogrammed desorption performed after cycling experiments with C3H6 evidenced the presence of NH3 and/or NH3-precursor intermediates on the surface. These surface species were formed as a result of reactions between NO and C3H6 during the rich as well as lean phases, but started to be used for NO reduction only when all the stored hydrocarbons were depleted. When fed together, the contributions of C3H6 and NH3 to the cycle-averaged NO conversion were essentially additive. However, temporally resolving N-2 formation using isotopically-labeled NO and a mass spectrometer revealed that C3H6 actually inhibited reactions between NO and feed NH3 until well into the subsequent lean phase, i.e., until the stored hydrocarbons were depleted. This study highlights the importance of controlling lean/rich cycling time partitioning to alleviate the impact of the inhibiting effect of C3H6 on NH3 chemistry and achieve the maximum NO reduction possible over the SCR catalyst in coupled LNT-SCR systems. (C) 2013 Elsevier B.V. All rights reserved.