The petroleum industry tends to paint an optimistic picture with respect to future petroleum availability. In order to anticipate demand, the size of connected volume of hydrocarbon of fields needs to be known. During the early stage of life of a reservoir, due to the lake of certain data, connected volume of hydrocarbon is usually based on analogues or rules of thumb and not detailed reservoir modeling. Therefore, there is a great incentive to produce physically-based methodologies to make an estimation of connected volume of hydrocarbon. Percolation theory is used to estimate the connected volume of hydrocarbon very fast. Furthermore, the result has been validated against areal field dataset.