폴리솔베이트 비이온성계면활성제를 함유한 3성분계의 상거동

정진기; 신도근; 이진희; 남기대

Journal of the Korean Industrial and Engineering Chemistry, Vol.8, No.4, 617-623, August, 1997

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폴리솔베이트 비이온성계면활성제를 함유한 3성분계의 상거동

The Phase Behavior of Ternary System Containing Polysorbate Nonionic Surfactants

정진기, 신도근, 이진희, 남기대

초록

폴리솔베이트-핵산올-물의 3성분계의 상거동에 관한 메카니즘을 조사한 것으로, 등방성인 미셀영역에서 비등방성인 모자이크 맥정상을 편광현미경에 의해 관찰하였다. 액정상 및 다른 상들은 약 20∼70 wt% 범위에서 관측되었으며, 이 영역에서는 보다 안정한 유화계나 분산계의 포뮬레이션에 대한 기본적인 데이터를 제공할 수 있다. 알킬기의 탄소수 증가에.따라 3상 영역이 감소한 반면에, 2상 영역이 증가되었으며 비등방성 액정상은 관찰되지 않았다.

In this study, the mechanism on the phase behavior of polysorbate nonionic surfactants was investigated. In the temary system containing water, hexanol as a polar oil and surfactant, the phase behaviors ranging from micellar region to occurrence of liquid crystal phase were observed by crossed microscope. As results, fine mosaic texture of liquid crystal phase and other phases were examined in the range of 20∼70 wt%. This range if thought to give information about the basic data for the formulation of more stable emulsifying systems or dispersed systems. According to the alkyl chain length, three phase region diminished, whereas two phase range increased without an observation of the anisotropic liquid crystalline phase.

[References]

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Haue E, Qutubuddin S, J. Polym. Sci., 26, 429 (1988)
Scamehorn JF, Harwell JH, "Surfactant Based Separation Processes," Marcel Dekker, New York (1989)
Shah DO, Schechter RS, "Improved Oil Recovery by Surfactant and Polymer Flooding," Academic Press Inc., New York (1977)
Karstrom G, J. Phys. Chem., 89, 4962 (1985)
Kunieda H, Shinoda K, J. Colloid Interface Sci., 42, 371 (1973)
Shinoda K, Saito H, J. Colloid Interface Sci., 30, 258 (1969)
Kunieda H, Shinoda K, Fragrance J., 17, 24 (1989)
James RJ, Goldemberg RL, J. Soc. Cosm. Chemists, 11, 461 (1960)
Sagitani H, J. Am. Oil Chem. Soc., 58, 738 (1981)
Kunieda H, Haishima K, J. Jpn. Oil Chem. Soc., 38, 642 (1989)
Uchio N, Solans C, Kunieda H, J. Jpn Oil Chem. Soc., 42, 31 (1993)
Becher P, "Emulsion Theory and Practice," Reinhold, New York (1975)
Shinoda K, Saito H, J. Colloid Interface Sci., 26, 78 (1968)
Kunieda H, Shinoda K, J. Phys. Chem., 82, 1711 (1978)
Rosen MJ, Li ZP, J. Colloid Interface Sci., 97, 456 (1984)
McBain JW, J. Chem. Soc., 127, 851 (1926)
Rosevear FB, J. Soc. Cosm. Chemists, 19, 581 (1954)
Winsor PA, Chem. Rev., 68, 1 (1968)
Tiddy GJT, Phys. Reports, 57, 1 (1980)
Booth F, Proc. R. Soc. London A, 203, 533 (1950)
Tanford C, J. Phys. Chem., 78, 2469 (1974)
Husson F, Mustachi H, Luzzati V, Acta Crystallogr., 6, 668 (1960)
Israelachvili IN, Mitchell DJ, Ninham BN, J. Phys. Faraday Trans. II, 72, 1525 (1976)

[1] Kandori K, Konno K, Kitahara A, J. Colloid Interface Sci., 115, 579 (1987)

[2] Haue E, Qutubuddin S, J. Polym. Sci., 26, 429 (1988)

[3] Scamehorn JF, Harwell JH, "Surfactant Based Separation Processes," Marcel Dekker, New York (1989)

[4] Shah DO, Schechter RS, "Improved Oil Recovery by Surfactant and Polymer Flooding," Academic Press Inc., New York (1977)

[5] Karstrom G, J. Phys. Chem., 89, 4962 (1985)

[6] Kunieda H, Shinoda K, J. Colloid Interface Sci., 42, 371 (1973)

[7] Shinoda K, Saito H, J. Colloid Interface Sci., 30, 258 (1969)

[8] Kunieda H, Shinoda K, Fragrance J., 17, 24 (1989)

[9] James RJ, Goldemberg RL, J. Soc. Cosm. Chemists, 11, 461 (1960)

[10] Sagitani H, J. Am. Oil Chem. Soc., 58, 738 (1981)

[11] Kunieda H, Haishima K, J. Jpn. Oil Chem. Soc., 38, 642 (1989)

[12] Uchio N, Solans C, Kunieda H, J. Jpn Oil Chem. Soc., 42, 31 (1993)

[13] Becher P, "Emulsion Theory and Practice," Reinhold, New York (1975)

[14] Shinoda K, Saito H, J. Colloid Interface Sci., 26, 78 (1968)

[15] Kunieda H, Shinoda K, J. Phys. Chem., 82, 1711 (1978)

[16] Rosen MJ, Li ZP, J. Colloid Interface Sci., 97, 456 (1984)

[17] McBain JW, J. Chem. Soc., 127, 851 (1926)

[18] Rosevear FB, J. Soc. Cosm. Chemists, 19, 581 (1954)

[19] Winsor PA, Chem. Rev., 68, 1 (1968)

[20] Tiddy GJT, Phys. Reports, 57, 1 (1980)

[21] Booth F, Proc. R. Soc. London A, 203, 533 (1950)

[22] Tanford C, J. Phys. Chem., 78, 2469 (1974)

[23] Husson F, Mustachi H, Luzzati V, Acta Crystallogr., 6, 668 (1960)

[24] Israelachvili IN, Mitchell DJ, Ninham BN, J. Phys. Faraday Trans. II, 72, 1525 (1976)