Inorganic Chemistry, Vol.53, No.5, 2361-2363, 2014
Redox Modulation of Magnetic Slow Relaxation in a 4f-Based Single-Molecule Magnet with a 4d Carbon-Rich Ligand
A ruthenium carbon-rich-based ligand that brings redox reversibility to a dysprosium-based single-molecule magnet is reported. Long-distance perturbation of the 4f ion is achieved upon oxidation, resulting in an overall enhancement of the magnetic slow relaxation.