Electric field plays a key role in producing required nanofibers in electrospinning. This study aims to improve the electric field distribution of the multijet spinning system by designing the spinneret configuration. A novel 19-hole multistep electrospinning configuration is presented. The simulation results show that the electric field strength at the central position is intensified due to the protuberant step on the spinneret, and therefore more uniform electric field is obtained compared with the 19-hole flat spinneret. We demonstrate that the multistep spinneret configuration produces finer fibers and more continuous fiber mats compared with the flat spinneret configuration because of the improved electric field distribution. Jet repulsion in the multijet electrospinning process is studied. It is found that the electric field line distribution, which is determined by the spinneret configuration, plays a dominant role in influencing jet repulsion. Applied voltage is the main factor responsible for jet repulsion for a given spinneret configuration.