In this paper, pyrolysis and hydroliquefaction processes were successively used to convert CCB-treated wood into bio-oil with respect to environment. Pyrolysis temperature has been optimized to produce maximum yield of charcoal with a high metal content (Cu, Cr, and B). The results obtained indicate that the pyrolysis at 300 degrees C and 30 min are the optimal conditions giving high yield of charcoal about 45% which contains up to 94% of Cu, 100% of Cr and 88% of B. After pyrolysis process, the charcoal has been converted into bio-oil using hydroliquefaction process. The optimization approach for the yield of bio-oil using a complete factorial design with three parameters: charcoal/solvent, temperature and hydrogen pressure was discussed. It is observed that the temperature is the most significant parameter and the optimum yield of bio-oil is around 82%. The metal analysis shows that the metals present in the bio-oil is very negligible. (C) 2012 Elsevier Ltd. All rights reserved.