This study used life cycle assessment software SimaPro 7.2 and impact assessment model IMPACT 2002+ to evaluate the environmental impact and benefits of a biochar cofiring supply chain used for electricity generation. The biochar was assumed to be produced by rice straw torrefaction and the case study was located in Taoyuan County, Taiwan. This supply chain may provide impact reduction benefits in five categories (aquatic ecotoxicity, terrestrial ecotoxicity, land occupation, global warming, and non-renewable energy) but cause higher impacts than coal firing systems in other categories. Damage assessment of cofiring systems indicated that damage to human health was higher while the damage categories of eco-systemluality, climate change, and resources were lower. Carbon reduction could be 4.32 and 4.68 metric tons CO2 eq/ha/yr at 10% and 20% cofiring ratios, respectively. The improvement of electricity generation efficiency of cofiring systems may be the most important factor for reducing its environmental impact. (C) 2012 Elsevier Ltd. All rights reserved.