Journal of Chemical Physics, Vol.103, No.9, 3864-3867, 1995
Anomalous Symmetries of the Rovibrational States of HO2 - Consequences of a Conical Intersection
We show that the geometric phase arising from a conical intersection of the lowest potential energy surfaces of HO2 causes its bending vibrational wave functions to be double-valued, which enables them to be locally symmetric on one side of the intersection and locally antisymmetric on the other.