화학공학소재연구정보센터
Bioresource Technology, Vol.166, 37-44, 2014
Catalytic upgrading of duckweed biocrude in subcritical water
Herein, a duckweed biocrude produced from the hydrothermal liquefaction of Lemna minor was treated in subcritical water with added H-2. Effects of several different commercially available materials such as Ru/C, Pd/C, Pt/C, Pt/gamma-Al2O3, Pt/C-sulfide, Rh/gamma-Al2O3, activated carbon, MoS2, Mo2C, Co-Mo/gamma-Al2O3, and zeolite on the yields of product fractions and the deoxygenation, denitrogenation, and desulfurization of biocrude at 350 degrees C were examined, respectively. All the materials showed catalytic activity for deoxygenation and desulfurization of the biocrude and only Ru/C showed activity for denitrogenation. Of those catalysts examined, Pt/C showed the best performance for deoxygenation. Among all the upgraded oils, the oil produced with Ru/C shows the lowest sulfur, the highest hydrocarbon content (25.6%), the highest energy recovery (85.5%), and the highest higher heating value (42.6 MJ/kg). The gaseous products were mainly unreacted H-2, CH4, CO2, and C2H6. (C) 2014 Elsevier Ltd. All rights reserved.