Chemical Engineering Journal, Vol.215, 202-208, 2013
Adsorptivity of heavy metals Cu-II, Cd-II, and Pb-II on woodchip-mixed porous mortar
Here, we developed a woodchip-mixed porous mortar (WPM) by mixing wood chips obtained from thinned Japanese cedar wood with porous mortar aggregates and evaluated the adsorption properties of the heavy metal ions Cu-II, and Pb-II on the WPM. The cation-exchange capacity (CEC) of cup-shaped WPM was approximately twice as large as that for wood chips. The saturation adsorption capacity of WPM for the heavy metal ions Cu-II, Cd-II, and Pb-II, determined by passing an aqueous solution of heavy metal ions, was 6, 23, and 7 times as much, respectively, as wood chips alone. Furthermore, the elution behavior of heavy metal ions adsorbed by WPM was studied by fractionation, wherein the metal speciation was divided into five classes by a sequential extraction method. The leached percentage of Fractions 1 and 2 combined, corresponding to the more easily eluted species of Cd-II, was higher than those of Cu-II and Pb-II. Finally, we found that the immersion of flat WPM in pure water and 3% sodium chloride for 1 year did not degrade the sample, which maintained its high adsorption capacity for heavy metal ions. (C) 2012 Elsevier B.V. All rights reserved.