화학공학소재연구정보센터
Journal of Chemical Physics, Vol.103, No.21, 9175-9186, 1995
Far-Infrared Permanent and Induced Dipole Absorption of Diatomic-Molecules in Rare-Gas Fluids .2. Application to the Co-Ar System
The general theory of far-infrared absorption of diatomic molecules in rare-gas fluids reported in Paper I is applied to the case of the CO-Ar system. The experimental absorption profiles of CO in Ar at three different densities (low-density gas, high-density gas, and liquid) are theoretically reproduced by considering the permanent dipole contribution and the four leading electrostatic multipole-induced dipole contributions. From these results an estimation of the quadrupole, theta, octupole, Omega and hexadecapole, Phi, moments of CO is given.