Naturally occurring dolomite is a low cost CO2 sorbent with superior performance to well known limestone. In this work, a microwave heating system was developed to carry out the CO2 capture experiment using a packed bed of calcined dolomite. Preliminary tests were performed in thermogravimetric analyzer (TGA) from which the calcination-carbonation temperatures of 750-700 degrees C were found as the suitable condition to obtain a conversion of 90% that could be sustained during 15 cycles of CO2 capture and release. Dynamic breakthrough curves of CO2 capture were developed by introducing different concentrations of CO2 (10-50 vol% in N-2) into a packed bed of calcined dolomite heating under microwave irradiation. The appropriateness of the developed system was further examined through its implementation for CO2 capture from a gas stream simulating air gasification producer gas. The regenerability of the bed was assessed in three cycles of calcination-carbonation (750-700 degrees C) in microwave where the sorbent revealed a high and relatively sustainable performance for CO2 capture. Kinetic studies based on shrinking core model deduced that the carbonation reaction mechanism in the packed bed was governed by a combination of chemical reaction and CO2 diffusion. (C) 2013 Elsevier B.V. All rights reserved.