Journal of Chemical Physics, Vol.104, No.9, 3325-3328, 1996
On the Relation Between the Wertheim 2-Density Integral-Equation Theory for Associating Fluids and Chandler-Silbey-Ladanyi Integral-Equation Theory for Site-Site Molecular Fluids
It is demonstrated that Chandler-Silbey-Ladanyi integral equation theory for the site-site molecular fluids is the limiting case of complete association of more general two-density integral equation theory for associating fluids developed by Wertheim. The analysis is presented for a site-site molecular system with any number and geometrical arrangement of the sites in the molecule and arbitrary type of the site-site pair interaction.
Keywords:DIRECTIONAL ATTRACTIVE FORCES;DIMERIZING HARD-SPHERES;SMITH-NEZBEDA MODEL;PERTURBATION-THEORY;THERMODYNAMICS;APPROXIMATION;FORMALISM;LIQUIDS