Journal of Chemical Physics, Vol.104, No.18, 6956-6963, 1996
Algebraic Approach to Molecular-Spectra - 2-Dimensional Problems
The Lie algebraic approach is extended to two-dimensional problems (rotations and vibrations in a plane). Bending vibrations of linear polyatomic molecules are discussed. The algebraic approach is particularly well suited to treat coupled bending modes. The formalism needed to treat coupled benders is introduced and a sample case, acetylene, is analyzed in terms of two coupled local benders.