화학공학소재연구정보센터
Journal of Chemical Physics, Vol.105, No.1, 62-67, 1996
A (1+1’)+1 Multiphoton Ionization Study of Cs2 in the 68500-73000Cm(-1) Energy Region - The 3D and 5S Rydberg States
The two color (1+1’)+1 resonance enhanced multiphoton ionization spectrum of CS2 has been recorded in the 68 500-73 000 cm(-1) excitation energy range, Strong bands were recorded in the 68 800-70 000 cm(-1) region and the upper states assigned to 3d and 5s gerade Rydberg states with quantum defects of 0.0 and 2.0, respectively. The two color spectra were recorded in both parallel and crossed polarization configurations to assist in state symmetry assignments. Some weaker features in the 70 500-71 500 cm(-1) region are most likely associated with vibronically induced transitions to a 5p Rydberg state.