Electrochimica Acta, Vol.58, 417-421, 2011
Metal-base transistor based on simple polyaniline electropolymerization
In this paper, we present a simple method for electropolymerization process that combines aniline-silane (C(6)H(5)NHC(3)H(6)Si(OMe)(3)) surface modified indium-tin-oxide (ITO) to prepare thin, polyaniline (PANI) films with good surface coverage. The modified surface enhances the growth of PANI film resulting in a smoother surface, dense, strongly adhered film, higher electropolymerization activity and stability than those deposited on unmodified ITO substrates. PANI film deposited on modified ITO substrate was used as a modified base terminal in a metal-base-transistor (MBT), which used tris(8-hydroxyquinoline) aluminum (Alq(3)) as an emitter layer, LiF as a buffer layer, and Al as a cathode. The MBT, tested at in ambient atmosphere, and without the presence of magnetic-field, has a comparable but stable current gain, 6.5 than that of a device with a sulfonated polyaniline (SPANI) based metal-base transistor. With this simple and easy electropolymerization method, the on-to-off current ratio achieved 6.9 x 10(4). (C) 2011 Elsevier Ltd. All rights reserved.