Cu2O is a p-type semi-conductor with a band gap of 2 eV, which is adapted for solar energy conversion and other advanced applications. Moreover it is based on abundant and non toxic elements and can be deposited by low cost electrodeposition. For this, structural and optoelectronic parameters have to be controlled. In this study, we proposed a systematical study of both structural and optoelectronic properties depending on electrodeposition parameters (pH and applied potential) and post-treatments. Influence of chloride ions is also investigated. Deposition potential was found to have a wide influence on the crystal orientation and the quality of the organization in the lattice and annealing was found to decrease the p-type doping level from a typical value of 1 x 10(18) cm(-3) to 5 x 10(17) cm(-3) as determined by using the semiconductor electrolyte junction. Addition of chloride in the electrolyte leads to a decrease of the structural quality of the layer but no modification of the doping level could be emphasized. Solid state heterojunctions with n-type ZnO were prepared leading to a photovoltaic conversion efficiency of 03%. (C) 2012 Elsevier Ltd. All rights reserved.