To produce micro- and mesoporous RH-derived activated carbons (ACs), a mixture of rice husk (RH) and beet sugar (BS) was carbonized to produce a precursor, which was subjected to the silica-leaching process and then CO2 activation. The silica, intrinsically present in natural RH, was used as a template for mesopores, and BS was used for additional development of micropores. The RH-derived ACs were prepared with the intention of application as the electrode materials of electrical double-layer capacitors. The RH-derived AC, exhibiting BET specific surface area of 1357 m(2)/g, total pore volume of 0.99 mL/g, and mesopore volume fraction of 44.4%, showed superior capacitive performance in both aqueous (1 M H2SO4) and organic (1 M TEMA center dot BF4/PC) electrolytes, in comparison with commercial microporous and mesoporous ACs with similar BET specific surface area (1200-1600 m(2)/g). The specific capacitance, evaluated by means of cyclic voltammetry using a three-electrode cell system at a scan rate of 5 mV/s, was 106 F/g for the aqueous electrolyte, and 114 F/g for the organic electrolyte. Higher specific capacitance in the organic electrolyte was obtained from the RH-derived AC, and was much higher than those of commercial ACs. The good compatibility with both the aqueous and organic electrolytes was attributed to the well-balanced micro- and mesoporosity. The role of the microporosity and mesoporosity on the capacitive performance of ACs in both electrolytes is also discussed. (C) 2013 Elsevier Ltd. All rights reserved.