Three-dimensional (3D) kenaf stem-derived porous carbon (PC) is considered to be a promising low-cost supporting material for application in energy storage devices. In this report, a simple and industry-scalable approach to prepare the hybrid (MnO2/3D-PC) of nanostructured MnO2 and 3D-PC has been developed. Such porous structures of the 3D-PC not only provided a conductive network to enhance the charge transport and mass transfer in the electrochemical process but also achieved a large MnLO2 mass loading capacity of 11.5 mg/cm(2,) which resulted in a high areal capacitance of 2.77 F/cm(2) at a scan rate of 1 mV/s. A specific capacitance of 416 Fig was obtained based on the mass loading of 2.52 mg/cm(2) at scan rate of 1 mV/s. Furthermore, the symmetrical supercapacitor based on the MnO2/3D-PC exhibited outstanding cycle performance with only 14% degradation after 1000 cycles under a large specific current density of 16 mA/cm(2). This research demonstrated that the 3D-PC was a good potential supporting material in energy conversion and storage devices. (C) 2014 Elsevier Ltd. All rights reserved.