The ionic liquids 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [EMim][NTf2] and 1-ethyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide, [EMpy][NTf2] have been studied as solvents for the extraction of toluene from mixtures with alkanes (heptane or cyclohexane). The liquid-liquid equilibria of ternary systems {heptane or cyclohexane + toluene+ [Emim[NTf2] or [EMpy][NTf2]} and {heptane + cyclohexane + [EMim][NTf2] or [EMpy[NTf2]} at 298.15K and atmospheric pressure were determined. The solute distribution ratio and selectivity derived from the tie-lines were used to determine if these ionic liquids can be used as extraction solvents. The tie-lines were satisfactorily correlated by means of the thermodynamic NRTL model for ternary systems with [EMpy][NTf2] and with NRTL and UNIQUAC models for the ternary systems with [EMim][NTf2]. (C) 2011 Elsevier B.V. All rights reserved.