The use of a surfactant mixture of natural and synthetic surfactants as additives in stabilizing coal-water slurry (CWS) formed from low rank Indian coals has been explored. The surface activities of the synthetic surfactants, hexadecyltrimethyl ammonium bromide (CTAB, cationic surfactant) and sodium dodecyl sulphate (SOS, anionic surfactant) are found to alter when various concentrations of natural surfactant, saponin (non-ionic surfactant) extracted from the fruits of Sapindous laurifolia are added to them independently. A considerable decrease in viscosity of CWS has been observed on the addition of saponin to the synthetic surfactants, CTAB/SDS (at 50:50 (w/w) for saponin:CTAB; 60:40 (w/w) for saponin:SDS systems). The mixture of anionic-nonionic is however, found to be more effective than the mixture of cationic-nonionic surfactants in reducing the apparent viscosity of the mixtures. The surface tension and contact angle data of the mixtures in solution suggest the high surface activity of the mixtures at these ratios. The rheological behaviors of CWS at weight concentrations varying from 55% to 65% wt.%, the static stability test, effect of pH, temperature, etc. have been studied. The slurries follow Bingham plastic behavior within these ranges of concentrations. A qualitative model of interaction of additive with a coal particle at the interface has been suggested. (C) 2013 Elsevier B.V. All rights reserved.