Journal of Chemical Physics, Vol.106, No.9, 3613-3622, 1997
The Solution of the Schrodinger-Equation by the (T,T’) Method Using the Wave Operator Procedure - Theory and Application to Molecular Photodissociation with Ultrashort Laser-Pulses
A new method for studying intense held photodissociation of molecules using ultrashort laser pulses is presented. The method is based on a generalized Floquet approach making use of the (t,t’) formalism and the wave operator theory. The usefulness of the scheme. for ultrafast photodissociation is illustrated by studying H-2(+) multiphoton dissociation with moderately intense and very short laser pulses.
Keywords:ABOVE-THRESHOLD-DISSOCIATION;TIME-DEPENDENT HAMILTONIANS;MULTIPHOTON IONIZATION;SCATTERING-THEORY;FIELDS;DYNAMICS;H-2+;STATIONARY;FORMALISM;H-2(+)