화학공학소재연구정보센터
Journal of Chemical Physics, Vol.106, No.12, 5159-5170, 1997
Theory of Solvent Effects on Electronic Absorption-Spectra of Rodlike or Disk-Like Solute Molecules - Frequency-Shifts
A theory, which has been advanced by the author and his co-workers, for frequency shifts of electronic absorption spectra of a nonpolar rodlike molecule in dilute nonpolar and polar solutions is extended so that it is applicable to a polar rodlike solute molecule and a nonpolar or polar disklike solute molecule. The theory takes into account higher-order multipole moments (in addition to a dipole) of the solute molecule, and its solution-phase polarizabilities are properly taken into account. Furthermore, it explains how the dispersive interaction is altered by the presence of permanent dipoles of the solvent.