The present work is devoted to investigation of the temperature and frequency dependencies of the different relaxing values in highly-viscous glycerol-like liquids. The consideration is based on microinhomogeneous structure conception, allowing us to give the consecutive explanation to both the thermodynamic and kinetic properties. The main attention is paid to analysis of heat capacity, dielectrical permeability and longitudinal sound velocity. The influence of measuring time and preparation one of highly-viscous states on observed values are discussed.