화학공학소재연구정보센터
Journal of Chemical Physics, Vol.106, No.14, 6187-6193, 1997
Measurement of the Splay-Bend Elastic-Constant in Lyotropic Ferronematic Liquid-Crystals - The Influence of the Bounding Surfaces
We report the first experimental investigation devoted to analyze the influence of a ferrofluid on the surface properties of lyotropic liquid crystals doped with magnetic particles. By means of optical methods, the bulk orientation of the director vs the temperature is determined, The theoretical analysis shows that near the nematic-isotropic transition, the thermodynamical model for the temperature surface transition works reasonably well. On the contrary, in the low temperature region near the lamellar-nematic transition, important deviations from the theoretical behavior are observed. In order to interpret our experimental data, we propose a simple phenomenological extension of the thermodynamical model that takes into account the different contributions to the surface energy and of the residual lamellar order in the nematic phase, We show, furthermore, that the effective splay-bend elastic constant depends on the ferrofluid doping concentration, in agreement with a recently proposed theory.