화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.32, No.16, 3682-3688, 2007
Evaluation of several low thermal expansion Fe-Co-Ni alloys as interconnect for reduced-temperature solid oxide fuel cell
Several low thermal expansion Fe-Co-Ni alloys including HRA 929C, Thermo-Span, EXP 4005 and Three-Phase were evaluated as interconnect for reduced-temperature solid oxide fuel cell (SOFC). The isothermal oxidation behaviors of the four alloys were determined at 800 degrees C in air corresponding to the SOFC cathode environment. The results indicate that the mass gains of HRA 929C and Thermo-Span increased continuously with oxidation time, and were higher than those of EXP 4005 and Three-Phase, both of which exhibited low oxidation rate after the first-week exposure due to the formation of a semi-continuous Al2O3 inner layer. Compared to the ferritic alloy Crofer 22 APU, these low thermal expansion alloys exhibited inferior oxidation resistance; however, the area specific resistance (ASR) of the, oxide scales thermally grown on these alloys was lower than that for Crofer 22 APU, as a result of the formation of a highly-conductive, Cr-free surface spinel layer. The promises and problems of these low thermal expansion alloys were discussed with regard to SOFC interconnect application. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.