The coupling of a photovoltaic generator and an electrolyser is one of the most promising options for obtaining hydrogen from a renewable energy source. Both are well known technologies, however, since the high variability of the solar radiation, an efficient coupling still presents some challenges. Direct or through a DC-DC converter couplings are the options in isolated applications. In this work, three models, respectively, for a photovoltaic (PV) generator, a controlled DC-DC converter and a complete proton exchange membrane (PEM) electrolyser have been designed by using Matlab/Simulink. A PV-electrolyser specific algorithm to search for the optimum and safe working point for both elements is presented. Simulation results demonstrate that the use of a controlled DC-DC converter with the proposed algorithm shows better adaptability to the variable radiation conditions than the other coupling options. Therefore, it leads to a better compliance between the electrolyser and the sizing of the PV generator. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.