화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.34, No.7, 3173-3184, 2009
Dynamic model and experimental results of a thermally driven metal hydride cooling system
This paper presents a dynamic model and experimental results of a metal hydride cooling system based on a coupled pair of reactors: a hot reaction bed (alloy LmNi(4.91)Sn(0.15)) and a cold reaction bed (Ti(0.99)Zr(0.01)V(0.43)Fe(0.09)Cr(0.05)Mn(1.5)). The driving power is waste heat removed at high temperature (130 degrees C). Metal hydride reactors can have interesting applications in thermal storage systems, refrigeration and heat pumps. The experimental setup is described, as well as the governing equations of the model. Correlations are used for the relationship between the equilibrium pressure, hydrogen concentration and temperature. An innovative approach is used for the modelling of hysteresis. The simulation results are compared and validated with experimental measurements during dynamic refrigeration cycles. (C) 2009 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.