A large excess of water and iodine is typically employed in the Bunsen reaction step of the sulfur-iodine thermochemical cycle in order to induce liquid-liquid phase separation of the two acid products. This paper presents an overview of some alternative routes for carrying out the Bunsen reaction. The use of a reaction solvent other than water is first discussed, and experimental results obtained with tributylphosphate are presented. Another approach is separation of the product acids by selective precipitation of insoluble salts, and the addition of lead sulfate as the precipitating agent is discussed in detail. Finally, the electrochemical Bunsen reaction route is investigated. All of these methods have the potential to reduce the iodine and/or water requirement of the sulfur-iodine cycle. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.