MgH2 is one of the most promising materials for hydrogen storage However, its rather slow hydrogen absorption and desorption kinetics and high dissociation temperature essentially limit its application in this field Nevertheless mixing Mg or MgH2 with small amount of transition metals or their oxides remarkably accelerates the hydrogen kinetics Recently a series of new hydrides Mg7TiHx, Mg-6 5NbHx and Mg6VHx of Ca7Ge type structure has been synthesized. The hydrogen desorption properties have been found to be better than for pure MgH2. Here, we report on the results of our theoretical study of the electronic structure of these new hydrides carried out within the framework of the full-potential, self-consistent linearized augmented plane-wave method We use these results, along with calculations of the heat of formation and relative stability, to discuss the bonding of these materials and their hydrogen-storage properties (C) 2010 Professor T Nejat Veziroglu Published by Elsevier Ltd All rights reserved