In this study, STS 316L (Stainless Steel 3161), STS 430, and Ti metal are investigated as metal bipolar plates for a direct methanol fuel cell (DMFC). The corrosion resistance of these materials is investigated by potentiodynamic and chronoamperometry tests. Their cell performance and long-term stability are then studied under a real fuel cell test. The corrosion resistance of the metal bipolar plates is in the order of Ti > STS 316L> STS 430. However, the results of the real fuel cell test differ from the results of the corrosion resistance. Ti shows the lowest performance due to a sharp performance decrease in ohmic loss regions, while STS 430 shows a lower performance decrease in ohmic loss regions. Although STS 430 has less resistance to corrosion than STS 316L in the simulated environment, STS 430 performs better as a metal bipolar plate for a DMFC than STS 316L, particularly, with regard to cell performance, cell resistance, and durability. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.