International Journal of Hydrogen Energy, Vol.35, No.20, 11052-11063, 2010
On the selection of metal foam volume fraction for hydriding time minimization of metal hydride reactors
Here we examine how the hydriding time of a metal hydride reactor (MHR) varies with the volume fraction, phi(mf), of a metal foam installed in the reactor. Technically, an experimentally validated mathematical model accounting for the hydrogen absorption kinetics of LaNi(5) is used to compute the heat and mass transport in a cylindrical MHR. We then demonstrate that, with a fixed amount of metal hydride powder sealed in the reactor, saving a relatively small fraction (say, 1%) of the MHR internal volume to accommodate a metal foam usually suffices to substantially facilitate heat removal from the reactor, thereby greatly shortening the MHR hydriding time. However, for a metal foam of fixed apparent size, increasing phi(mf) would reduce the metal hydride content, and hence the maximum hydrogen storage capacity, of the MHR. Consequently, if a prescribed amount of hydrogen is to be stored in the MHR, the hydriding time would decrease with increasing phi(mf) at first (due to heat conduction augmentation), reach a minimum at an "optimal" phi(mf) value, and then increase drastically due to metal hydride underpacking. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
Keywords:Metal hydride reactor;Heat conduction augmentation;Metal foam;Hydriding time;Hydrogen storage capacity