In this communication, we report the synthesis of helical carbon nanofibres (HCNFs) by employing hydrogen storage intermetallic LaNi(5) as the catalyst precursor. It was observed that oxidative dissociation of LaNi(5) alloy (2LaNis + 3/2O(2) -> La(2)O(3) + 10Ni) occurred during synthesis. The Ni particles obtained through this process instantly interacted with C(2)H(2) and H(2) gases, and fragmented to nanoparticles of Ni (similar to 150 nm) with polygonal shape. These polygonal shapes of Ni nanoparticles were decisive for the growth of helical carbon nanofibres (HCNFs) at 650 degrees C. TEM, SAED and EDAX studies have shown that HCNFs have grown on Ni nanoparticles. Typical diameter and length of the HCNFs are similar to 150 nm and 6-8 mu m respectively. BET surface area of these typical HCNFs has been found to be 127 m(2)/g. It was found that at temperature 750 degrees C, spherical shapes of Ni nanoparticles were produced and decisive for the growth of planar carbon nanofibres (PCNFs). The diameter and length of the PCNFs are similar to 200 nm and 6-8 mu m respectively. In order to explore the application potential of the present as-synthesized CNFs, they were used as a catalyst for enhancing the hydrogen desorption kinetics of sodium aluminum hydride (NaAlH(4)). We have found that the present as-synthesized HCNFs, with metallic impurities, indeed work as an effective catalyst. The pristine NaAlH(4) and 8 mol% as-synthesized HCNFs admixed NaAlH(4), at 160 degrees C-180 degrees C and for the duration of 5 h, liberate 0.8 wt% and 4.36 wt% of hydrogen, respectively. Thus there is an enhancement of similar to 5 times in kinetics when as-synthesized HCNFs are used as the catalyst. To the best of our knowledge, the use of hydrogen storage alloy LaNi(5) as the catalyst precursor for the growth of HCNFs has not yet been done and thus represents a new feature relating to the growth of HCNFs. Furthermore, we have shown that the as-synthesized HCNFs work as an effective new catalyst for improving the dehydrogenation kinetics of the complex hydride, NaAlH(4). Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.