화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.36, No.17, 10719-10726, 2011
A passively-fed methanol steam reformer with catalytic combustor heater
This paper presents a continuation of our work on our simple novel feeding method for a methanol steam reformer. Using a single heat source, a fixed ratio of water and methanol vapor can be fed into the reformer passively without fuel pumps. The feasibility of this method has already been verified using an electric heater and a catalytic combustor fueled with pure methanol is used at present. Machined on a copper plate, a catalytic combustor in a u-turn-channel was positioned under a two-turn serpentine channel reformer. Water/methanol feed ratios of 0.8-1.47 were managed under different reaction temperatures. Highly uniform temperature distributions throughout the reformer were demonstrated. With an increasing reaction temperature, the product composition varied from 71.5% H(2) to 0.26% CO to 73% H(2) and 0.45% CO. The methanol conversion exceeded 98% when the reaction temperature was higher than 292 degrees C and the water/methanol feed ratio was over 1.0. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.