Journal of Chemical Physics, Vol.107, No.5, 1668-1671, 1997
Resonances in the Photodepletion Spectrum of the Ba...Fch3 Weakly-Bound Complex
Fano type resonances were observed in the photodepletion action spectrum of the Ba...FCH3 complex. They can be interpreted as a result of a significant coupling between the bound excited potential of the complex and the (open channel) ionic potential leading to BaF*+CH3 reaction products.
Keywords:CHARGE-TRANSFER DISSOCIATION;VANDERWAALS COMPLEXES;PHOTOINITIATED REACTIONS;STATES;PHOTODISSOCIATION;EXCITATION;PHOTOLYSIS;AR