The effect of carbon nanofibres (CNFs) on the de/re-hydrogenation characteristics of 1:2 magnesium amide (Mg(NH2)(2)) and lithium hydride (LiH) mixture is investigated. It is found that the desorption as well as absorption characteristic of the 1:2 Mg(NH2)(2)/LiH mixture is improved with admixing of different shaped (planar and helical) CNFs separately. The different shaped CNFs were synthesized through catalytic decomposition of acetylene gas over LaNi5 alloy. The synthesized CNFs contain Ni-metal nano particles. Among two different types of nanofibres namely planar carbon nanofibres (PCNFs) and helical carbon nanofibres (HCNFs), the later was found to act as a better catalyst. The decomposition temperature of the pristine Mg(NH2)(2)/LiH mixture is similar to 250 degrees C, reduced to 150 and 140 degrees C for the PCNF and HCNF admixed Mg(NH2)(2)/LiH mixture respectively. The activation energy for dehydrogenation reaction was found to similar to 97.2 kJ/mol, which is further reduced to similar to 67 and similar to 65 kJ/mol for the PCNF and HCNF admixed Mg(NH2)(2)/LiH mixture respectively. The lowering of decomposition temperature and enhancement in desorption kinetics, with admixing of different shaped CNFs are described and discussed. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.