In this paper, we present a new route for recycling waste Mg with the production of MgH2 nanofiber, which is a promising candidate for energy storage and conversion used in Li-ion batteries and H-2 storing technologies. Highly pure MgH2 nanofibers were successfully manufactured from Mg-alloy swarfs (AM60B and AZ91D) via the hydriding chemical vapor deposition (HCVD) process. The possibility of recycling all types of Mg scraps using the HCVD process was demonstrated, which requires only a pretreatment of obtaining a dried raw material. The HCVD method shows many advantages over other methods in the synthesis of MgH2: it can produce MgH2 at low cost using waste Mg as the raw material, requires less energy, offers a high-purity product, and enables control over the growth of nanosized structures. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.