화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.37, No.22, 17078-17092, 2012
An experimental investigation of reverse vortex flow plasma reforming of methane
This paper focuses on the reforming of methane into hydrogen rich gas by means of gliding arc plasma stabilized in a reverse vortex flow. Parametric tests utilizing a 42 mm diameter reactor investigated the effects of electrode gap distance, reaction chamber exit diameter, steam input, methane input (fuel to oxygen ratio), and power input. Over the range of conditions tested, reactor performance was most sensitive to methane input. Decreasing the diameter of the reaction chamber exit impeded the performance of the reformer. A set of factorial tests determined the optimal operating conditions of the system to be at flow rates of 2 slpm nitrogen, 0.56 slpm oxygen, 1.25 slpm methane, an electrode gap distance of 34.5 mm, an outlet diameter of 12.65 mm, and a power input of 260 W. At these conditions the system yielded 83.3% hydrogen selectivity, 79.8% methane conversion and efficiency of 43.5%. Physical operating boundaries of the system defined by soot production and arc extinction were identified. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.