화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.37, No.24, 19365-19370, 2012
Integration design of membrane electrode assemblies in low temperature solid oxide fuel cell
In this paper, an integration design of membrane electrode assemblies in low temperature solid oxide fuel cells (LTSOFCs) is accomplished by using a mixed ionic-electronic conductor. The mixed ionic-electronic conductor is a composite material, LiNiCuZn oxides, Gd2O3 and Sm-doped CeO2 composited with Na2CO3 (LiNiCuZn oxides-NGSDC), which consists of ionic conductor, n-type and p-type semiconductors. The multi-phase composite material can also be used in single layer fuel cell (SLFC) to replace single-phase materials. A SLFC using the LiNiCuZn oxides-NSGDC composite exhibits an OCV of 1.05 V and maximum power density of 800 mW cm(-2), which is comparable to the cell performance of conventional LTSOFCs and much higher than that of SLFC reported before. The reasons leading to the good performance are porous structure of electrode and the matching of ionic conductor and semiconductor. Copyright (c) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.